H hiblot, i zieglerdevin, r fournet, pierrealexandre glaude. Steam reforming definition of steam reforming by the. Methane steam reforming, methanation and watergas shift. Hydrogen based fuel cells are considered to be attractive in modern applications for their high efficiency and ideally emissionfree use, in contrast. Typically, burner outer row firing is lower than innerrow firing. Steam reforming of methane in a synthesis gas from biomass gasification h hiblot, i zieglerdevin, r fournet, pierrealexandre glaude to cite this version. Redefining steam methane reformer performance in hydrogen. Methane steam reforming reaction behaviour in a packed. Co are also active for the methane steam reforming 25. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. Due to its maturity, high efficiency, and relatively low cost, steam reforming is considered a viable option for supporting a future hydrogen economy. In steammethane reforming, methane reacts with steam under 325 bar pressure 1 bar 14. Smr is a costeffective and energy efficient way of producing hydrogen.
Specifically, we look at the deactivation of a ni catalyst due to coke formation, its high operating temperature requirements, and the high steam to methane h2och4 ratio. The reaction called dry reforming reaction produces carbon monoxide and hydrogen from methane and co 2. The main purpose of this technology is hydrogen production. Steam reforming free download as powerpoint presentation. Carbon formation and active site of alumina supported. In this study, we approach several common problems with the nicatalyzed methane steam reformation reaction msr using a twopronged approach combining density functional theory dft calculations with experimental work.
On the catalytic aspects of steammethane reforming a literature. Department of energy doe is investigating employing co2capture technologies combined with texaco and shell integrated gasification combinedcycle igcc power systems that produce both merchant hydrogen and electricity. For more than 40 years the catalyzed hydroearbon steam reforming reaction has been of commercial value. A life cycle assessment lca of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases, as well as other major environmental consequences. According to this invention, substantially the entire stream of treated boiler feed water leaving the deaerator is pressurized and sent to the boiler feed water heater at elevated pressures. This process contains two chemical reactions which ultimately convert water and methane usually in the form of natural gas into pure hydrogen and carbon dioxide. Steam methane reforming overview of steam methane reforming.
The process consists of two steps involving the decomposition of methane to co free hydrogen and surface carbon in the first step followed by steam gasification of this surface carbon in the second step. Reducing reaction temperature, steam requirements, and. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. The dominate steam reforming processes convert natural gas, lpg or naphtha, with water vapor in the presence of a nickel catalyst, into a hydrogenrich. Pdf the steam reforming process converts hydrocarbons into mixtures of. This is achieved in a reformer which reacts steam at high temperature and pressure with methane. The first units commissioned in the 1930s were run on light hydrocarbon feedstock at atmospheric pressure l, it took until 1962 for a 15atm steam reformer to come onstream in the united kingdom using liquid hydrocarbon feedstock 24. This name is commonly retained even when other feedstocks e. Abstract methane steam reforming experiments were carried out at atmospheric pressure for temperatures between 873 and 1073 k and by varying the partial pressure of methane and steam to achieve s. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Kinetics, catalysis and mechanism of methane steam reforming. Hydrogen generation by steam reforming mahler ags gmbh duration. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water.
Steam methane reforming is the most widely used process for the generation of hydrogen. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. The present invention provides a steam methane reforming process and system utilizing an integrated steam system having both high pressure and low pressure steam circuits. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. Thermodynamic analysis of steam reforming of methane with. Under these conditions, the catalyst presents the average h2co. Jul 28, 20 steam reforming the basics of reforming 1.
The steam methane reforming process can be broken down into five distinct steps. Onsite hydrogen generation by steam methane reforming. Hydrogen production by steam reforming chemical engineering. Prepared samples were tested when unreduced and reduced prior to reaction for methane dry reforming and methane steam reforming reactivity. Hydrogen is also expected to play an important role as a carbonfree. Comparison of catalyst geometries for methane steam. Nov 27, 2012 a nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst at 150200 c. Meanwhile, the steam methane reformer refers only to the fired chemical reactor in which reaction takes place. Catalytic steam reforming an overview sciencedirect topics. Steam reforming of natural gas sometimes referred to as steam methane reforming smr is the most common method of producing commercial bulk hydrogen. Actually, a small amount of steam is introduced into the process, but this reaction is a bigger endothermic reaction than the catalytic steam reforming reaction. The hydrogen produced contains less than 10 ppmv of carbon oxides, but can achieve only a hydrogen concentration between 92 and 97 vol% depending on the severity of the reforming reaction. Methane steam reforming reaction behaviour in a packed bed. Introduction an efficient and reliable way to produce hydrogen gas.
To obtain a comprehensive picture of the three main reforming methods via plasma chemistry, methane steam reforming in terms of electroninduced chemistry and thermochemistry should be properly addressed in systematic experiments. Low temperature methane steam reforming for hydrogen. This represents a high efficiency strategy for using the coalresource base while being sensitive to the current motivation to reduce greenhouse gas emissions. Steam reforming of methane in a synthesis gas from biomass gasification. Key applications for hydrogen is as a carbon free fuel and as a fuel for hydrogen driven. Photocatalytic steam reforming of methane over sodium. Steam plasma with very high enthalpy and low mass flow rate was produced in a dc arc discharge which was in direct contact with water vortex surrounding the arc column. Sulfur deactivation effects on catalytic steam reforming of. Steam reforming reactions the conversion of hydrocarbons to a mixture of co, co and h2 two reactions. Pdf hydrogen from steammethane reforming with co 2. A method for the production of clean hydrogen is demonstrated. Steam methane reforming is the most common and economical way to make hydrogen. Onsite hydrogen generation by steam methane reforming what its like to be a hydrogen molecule duration.
The methaneis then reacted with steam at a relatively high temperature, using nickel oxide as a catalyst. Experimental and modeling study of hydrogen production from catalytic steam reforming of methane mixture with hydrogen sul. Steam methane reforming hydrogen production air liquide. Mar 30, 2015 methane steam reforming pdf document methane steam reforming. The unfavorable effect of ethylene on the reaction decreases with an increase in the ratio of the catalytic surface area to the free reaction volume. The activity of the photocatalysts was much influenced by metal cation doped into the bulk of natao 3, the crystallites size of natao 3, and metal nanoparticles loaded on the surface. This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen. Steam methane reforming definition of steam methane. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. C2pt catalyst process technology by gerard b hawkins managing director 2. Experimental and modeling study of hydrogen production. Pdf simulation, sensitivity analysis and optimization of.
Intrinsic kinetics intrinsic rate equations were derived for the steam reforming of methane, accompanied by watergas shift on a ni mga1204 catalyst. Steam reforming of methane in a temperaturecontrolled. The other major fundamental methane reforming method, besides dry reforming and partial oxidation, is steam reforming. Methane steam reforming on supported nickel based catalysts. Natural gas reforming, steam methane reforming, autothermal reforming, gproms, modelling, optimisation. Life cycle assessment of hydrogen production via natural gas. Mechanistic considerations for methane steam reforming msr were derived onthebasisoflangmuirhinshelwood. Steam reforming of methane in a synthesis gas from biomass. Benchscale steam reforming of methane for hydrogen. Methane steam reforming an overview sciencedirect topics. History of synthesis gas in 1780, felice fontana discovered that combustible gas. The model of the steam reforming process used was developed using equilibrium reactor type.
On the catalytic aspects of steammethane reforming a. Thermodynamic analysis of steam reforming of methane has been studied by method of gibbs free energy minimization for hydrogen or syngas production in the ranges of steam to methane from 0. The steam methane reforming process for producing chemical hydrogen is the most common manufacturing process for hydrogen and is vital to the petroleum refining industry. Water enters the furnace, producing steam at a very high temperature. Catalytic reforming of methane in the presence of co2. Co2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over ndcoo3 perovskitetype mixed metaloxide catalyst.
Methane steam reforming has been simulated, analyzed and optimized with the aid of aspen plus, in this work. Pdf the production of synthesis gas by steam reforming of. These onsite units provide a compact, efficient, and flexible alternative to other hydrogen supply schemes. International journal of hydrogen energy, elsevier.
H298k 75 kjmol ch4 several parameters have been defined, including dimensions and information on the porous medium. Steam reforming of hydrocarbons is the most feasible route today. Steam reforming of methane, ethane, propane, butane, and. This work uses finite element software comsol multiphysics 4. For many refiners, sulfurfree natural gas ch4 is not always available to. A large number of detailed reaction mechanisms were considered. Sometimes referred to as steam methane reforming smr, this process involves the heating of methane ch4 with steam, in the presence of a catalyst, to create hydrogen h2 and carbon oxide byproducts. Steam methane reforming desulfurizes light hydrocarbon feeds and converts them into synthesis gas which is then purified by co2 scrubbing and methanation or through pressure. The steam reforming of methane consists of three reversible reactions. The equilibrium composition out of the steam reformer is shown in fig. Steam plasma methane reforming for hydrogen production. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Advanced steadystate modelling and optimisation of natural gas reforming reactors.
Press release hydrogen market by type steam methane reforming, partial oxidation of oil, coal gasification, electrolysis of water global opportunity analysis and. Steam reforming before development of psa with a polybed psa system, the co 2 removal system and methanator become redundant. More specifically, it relates to an exposed flanged tube outlet of a reformer designed to mitigate metal dusting corrosion, dew point condensationrelated metal fatigue and cracking, and overtemperature induced metal failures such as hydrogen attack. Hydrogen market by type steam methane reforming, partial. A main reaction in catalytic reforming not to be confused with catalytic. The design of the steam reforming process is in part dictated by these constraints. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Steam reforming is endothermicthat is, heat must be supplied to the process for the reaction to proceed.
Research on steam reforming technology commonly uses ch 4 as a model substance for natural gas. In the first part of the analysis, a closed system in which steam reforming reactions take place is considered, and elemental compositions leading to carbon formation are determined. Lca is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes. Steam methane reforming essay sample new york essay. Steam methane reforming is a widelyused process to convert methane into a mixture of hydrogen and carbon monoxide syngas. Mechanistic investigation of methane steam reforming over. Breaking of the cbond to the nistep on the free surface.
Us10384183b2 steam methane reformer tube outlet assembly. Figure 6, based on equilibrium calculations obtained using the freeenergy. And finally, in chapter 6, a selection of present trends in reforming catalyst research is discussed. Reactions of methane with water and co 2 in thermal plasma generated in a special plasma torch with a waterstabilized arc were investigated. Steam reforming of methane, ethane, propane, butane, and a sulfur free natural gas is studied over a rhodiumbased monolithic honeycomb catalyst.
Life cycle assessment of hydrogen production via natural. Presentation about steam reforming modeling and simulatino. In steam methane reforming, methane reacts with steam under 325 bar pressure 1 bar 14. This process is called steam reforming, and was already discussed in chap. Economic analysis of hydrogen production from steam reforming. The present invention relates a steam methane reformer tube outlet assembly and a method of assembling or retrofitting same. Kjersti omdahl christensen steam reforming of methane on. The effects of reaction parameters, including reaction temperature and space velocity, on hydrogen production via steam reforming of methane srm were investigated using lab and benchscale. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to produce hydrogen on a large scale. Nial2o4 in the reduced and unreduced state as well as nial4o7 in the reduced state are active and stable for methane dry reforming due to the presence of 4fold coordinated oxidized nickel. Differences in the nature of active sites for methane dry. Methane steam reforming is a chemical process to produce hydrogen and synthesis. After the initial reforming reaction, the steam undergoes a watergas shift reaction, which converts carbon monoxide co into. Pdf benchscale steam reforming of methane for hydrogen.
Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. It should be noted here that the reforming of methane withco 2. In the second part, results of an industrial steam reformer simulation are used to locate, inside the reactor.
Advanced modelling and optimisation of natural gas. Steam reforming of natural gas sometimes referred to as steam methane reforming smr is the most common method of producing commercial bulk hydrogen at about 95% of the world production of 500 billion m 3 in 1998. The production of synthesis gas by steam reforming of methane,brief descritpion about synthesis gas production. Hydrogen is used in the industrial synthesis of ammonia and other chemicals. Membranes free fulltext hydrogen production via steam.